The Champions League takes centre stage on Tuesday with the heavyweight clash of Paris Saint-Germain and Barcelona a tantalising prospect in the French capital.Liverpool and Manchester City have home assignments while an out-of-sorts Napoli face Bodo/Glimt in Naples. There is also lots of action from the EFL, with Wolves welcoming Portsmouth in the lone Championship game.Below we’ve got a bet of the day, an intriguing bet builder and a healthy-looking acca to check out.talkSPORT BET – Bet £10 Get £40 + A Boost Token – CLAIM HERE*Tuesday Football TipsBet of the DayParis Saint-Germain to beat Barcelona & both teams to score @ 2/1Paris Saint-Germain looked irresistible at times in their win over Manchester City last week, the two-time European champions showcasing their array of attacking prowess with a three-goal first-half salvo.Luis Enrique’s side have scored 10 times in two Champions League games. Barcelona haven’t slouched either, scoring nine in wins over Feyenoord and Galatasaray.The summer signing of Rodri was an attempt to shore up a Barca midfield that has been found wanting against truly elite opponents. They may be contenders for this title come the spring but it is a work in progress and they have conceded multiple goals in four of their last seven La Liga games.PSG have won three of the five meetings since 2021, with both teams scoring in all instances. They can win this early-season skirmish at the Parc des Princes.Bet builderLiverpool to beat Villarreal, Bradley Barcola to Score Anytime & Alexander Isak 2+ Shots on Target @ 7/2Liverpool are going for three Champions League wins on the bounce but they have yet to keep a clean sheet after surrendering four goals in the wins over Atletico Madrid and LASK. The Reds have just one shutout in five across all competitions.Villarreal were beaten 3-2 in Dortmund on matchday one before impressing in beating Napoli 3-1 at El Madrigal last week. Their record in England is poor, with six losses and two draws in eight attempts, excluding qualifiers. The Yellow Submarine can fashion a goal but may sink at Anfield.Bradley Barcola bagged a hat-trick at LASK and with better finishing the French forward could have got another treble at Brentford on Saturday. He’s getting into great positions and can find the net again.After a tough first season, Alexander Isak is making good strides for the Reds now. He was the match-winner at the weekend and can at least test the visiting goalkeeper this time.AccaLiverpool to beat VillarrealOver 3.5 Goals in PSG vs BarcelonaBoth teams to score in Wolves vs PortsmouthBodo/Glimt or Draw double result vs Napoli @ 6/1Liverpool have won their last three meetings with Villarreal and the Spaniards have just two La Liga wins in nine this season, while their record in England is lamentable. Andoni Iraola’s side should come out on top.The game of the day in Paris features a PSG side with 10 goals in their last three games, having hit six in their Champions League opener last month, against a Barcelona outfit averaging 4.36 goals per game this season. Two of the previous three head-to-heads have featured five goals.Wolves are back on track in the Championship after a gutsy come-from-behind win at Burnley on Friday and the Old Gold face a Portsmouth side with momentum after wins against Sheffield United and Norwich. Both teams can net at Molineux, where Wolves have just one clean sheet in four so far.Bodo/Glimt travel to Napoli in the Champions League. Massimiliano Allegri’s side lost at Venezia on Saturday, a third Serie A defeat from seven games and are staring at four straight defeats in major European competition for the first time. The Norwegian beat Inter Milan home and away in the first knockout round last season and can leave Naples with something.talkSPORT BET – Bet £10 Get £40 + A Boost Token – CLAIM HERE*Odds correct at time of publish and subject to change.Commercial content notice: Taking one of the bookmaker offers featured in this article may result in a payment to talkSPORT. 18+. T&Cs apply. Gambleaware.org.Remember to gamble responsiblyA responsible gambler is someone who:Establishes time and monetary limits before playingOnly gambles with money they can afford to loseNever chase their lossesDoesn’t gamble if they’re upset, angry or depressedGamCare – www.gamcare.org.ukGamble Aware – www.gambleaware.orgFor help with a gambling problem, call the National Gambling Helpline on 0808 8020 133 or go to www.gamstop.co.uk to be excluded from all UK-regulated gambling websites.