Our Valencia vs Barcelona predictions and preview considers Hansi Flick’s team’s attempt to maintain their 100 percent record at the start of the 2026/27 campaign.Valencia vs Barcelona head to head overviewDate: Sunday 6th September.Kick-off: 3.15pm.Venue: Estadio de Mestalla, Valencia, Spain.Where to watch: Premier Sports 2.Valencia vs Barcelona quick tipsBarcelona to win and both teams to score – 13/8 with BoyleSportsOver 3.5 goals – Evens with 247BetRaphinha to score any time – 10/11 with bet365Valencia vs Barcelona predictionsThere is a long way to go this season, but the early signs suggest Barcelona have lost none of their hunger.The debate over the summer was whether the Blaugrana would have the same desire to win the La Liga title after triumphing two seasons in a row.Some felt Hansi Flick’s team would turn their focus to the Champions League, and that may still prove to be the case. But Barcelona do not intend to give up their domestic crown without a fight.We are only three games in, but the La Liga table already has a familiar look: Barcelona first, Real Madrid second and Atletico Madrid third.Only Barca and Madrid have nine points to their name, with the former’s superior goal difference giving them the edge in the early standings.It has been a blistering start from the champions, who have beaten Elche (5-0), Athletic Bilbao (2-0) and Rayo Vallecano (5-2) with a minimum of fuss.The worrying thing for the rest of the division is that Barcelona might get even better from here.Rodri, the standout performer at World Cup 2026, has yet to start a game for his new club following a summer switch from Manchester City. Fellow midfielder Frenkie de Jong is currently injured, as is academy product Gavi.Valencia vs Barcelona tipsBarcelona head to the Estadio de Mestalla to face Valencia this La Liga weekend.More joy for BarcelonaBarcelona can outscore anyone in Europe on their day, so conceding one or two goals is not necessarily fatal to their chances of victory.Needless to say, Hansi Flick would prefer to see his team keep a clean sheet every game. But he is a manager who would rather win 4-2 than 1-0.The fact that Rayo Vallecano scored twice against Barcelona on Monday night gives Valencia hope.But it is difficult to see the home team getting anything from this game given how well Barcelona have been playing already. Tip Barcelona to win and both teams to score at 13/8 with BoyleSports Goals await at MestallaTwo out of Barcelona’s three games in 2026/27 have contained at least four goals, and we reckon Sunday’s showdown with Valencia will follow suit.Throughout Hansi Flick’s time at the Camp Nou, Barca have adopted an ultra-attacking approach.That has at times cost them in the Champions League, most notably against Inter in the semi-finals of 2024/25, but it has served them well overall.Barcelona are not about to change, at least not in La Liga, so we expect goals when they face Valencia on matchday four. Go for over 3.5 goals at evens with 247Bet Raphinha in fine formRobert Lewandowski and Ferran Torres, Barcelona’s two most natural central strikers last season, both departed the club in the summer transfer market.There has been much debate over who will lead the line this term. Gabriel Jesus is now another contender following his recent move from Arsenal.For now, though, the role is Raphinha’s to lose. The Brazil international has had a fantastic start to the season through the middle, scoring five goals in his first three appearances. Raphinha’s confidence is sky-high and he will cause Valencia plenty of problems in this one. Back Raphinha to score any time at 10/11 with bet365 Valencia vs Barcelona predicted lineupsValencia expected lineup: Dimitrievski; Rioja, Martinez, Diakhaby, Tarrega, Vazquez; Ugrinic, Pepelu, Sato; Guerra, Duro.Barcelona expected lineup: J. Garcia; Kounde, Cubarsi, Christensen, Espart; Bernal, Pedri; Yamal, Olmo, Gordon, Raphinha.Valencia vs Barcelona latest oddsFind the latest Valencia vs Barcelona betting odds here. All odds are provided by our recommended football bookmakers and are subject to change.Valencia: 6/1 with BoyleSportsDraw: 14/3 with 247BetBarcelona: 1/3 with bet365More La Liga predictionsWe have plenty more La Liga predictions and picks – find our latest betting tips from expert punters in our match preview overview.Important historical facts about Valencia vs Barcelona for bettingBarcelona lost their last game against Valencia, but they previously won five games in a row against their upcoming opponents – including by emphatic scorelines like 6-0, 5-1 and 7-1. Barcelona have scored in their last 13 meetings with Valencia.Last meeting: 23rd May 2026; Valencia 3-1 Barcelona.Last 6 matches: Valencia wins – 1; Barcelona wins – 5; Draws – 0.About the authorGreg LeaGreg Lea is a freelance football writer from London. He predominantly covers the Premier League and has had work published by the Guardian, FourFourTwo, ESPN and others.Follow Greg on X: @GregLeaFootballCommercial content notice: Taking one of the bookmaker offers featured in this article may result in a payment to talkSPORT. 18+. T&Cs apply.Remember to gamble responsiblyA responsible gambler is someone who:Establishes time and monetary limits before playingOnly gambles with money they can afford to loseNever chase their lossesDoesn’t gamble if they’re upset, angry or depressedGamcare – www.gamcare.org.ukFind our detailed guide on responsible gambling practices here.For help with a gambling problem, call the National Gambling Helpline on 0808 8020 133 or go to www.gamstop.co.uk to be excluded from all UK-regulated gambling websites.