Harry Kane scored a stoppage-time winner for Bayern Munich shortly after a rare missed penalty in the DFB-Pokal.Bayern travelled to German third tier side SV Wehen Wiesbaden on Wednesday night for what was very nearly an embarrassing defeat.Kane was unable to score a 32nd consecutive penalty in surprise scenesAFPKane netted the opener from 12 yards before Michael Olise added a second, but Fatih Kaya scored two goals to level it for Wehen.With 14 minutes left on the clock, Kane had an opportunity to restore Bayern’s lead with another penalty.However, Florian Stritzel saved his effort and then his follow-up as Wehen held on against the odds.Kane missed his first penalty since 2022 when he fired over the crossbar for England in their World Cup quarter-final exit to France.The 32-year-old had scored from 31 consecutive attempts afterwards, which included Bayern’s first against Wehen.But the England captain overcame the setback to score the winner in the fourth minute of second half stoppage-time.He headed in from Josip Stanisic’s cross to ensure Bayern beat a side who sit 41 places below them in German football.Kane’s penalty recordKane has scored a stunning 90 penalties from a possible 102 for club and country throughout his career.Most of his successful attempts came in Tottenham colours, with 42 being netted during his legendary spell in north London.The striker has scored 23 for England and a further 22 at Bayern since he signed in 2023.A sense of shock could be seen on his face after his missed effortAFPBut Kane emerged as the Bayern hero with just minutes remainingGettyKane has made just three appearances this season but already hit six goals in what has been a blistering start.Bayern began their 2025/26 campaign by beating VfB Stuttgart 2-1 to win the 2025 Franz Beckenbauer Supercup, with Kane scoring first.He then netted a second half hat-trick against RB Leipzig as the Bundesliga holders emphatically kickstarted their title defence.Kane is on course to scored his 100th goal for Bayern before the end of 2025.The ex-Spurs man could also make his 100th appearance for the club this weekend when they travel to Augsburg on Saturday.After the Bundesliga clash, he is expected to spend the international break with England for their opening two World Cup qualifiers.Kane is on course to hit two centuries for Bayern in the coming weeksThomas Tuchel names his squad on Friday for their fixtures against Andorra and Serbia.Should Kane play in both matches, he will overtake Ashley Cole and Bobby Moore to reach 109 caps for the Three Lions.