How do organic solar cells work on the inside? The answer lies in structures far too small to see—and difficult to access even with advanced techniques. So far, researchers have relied mainly on X-ray methods to understand how molecules are arranged within these materials and how this order can be optimized for high efficiency. While powerful, X-rays provide only a spatially averaged picture. Electrons, in contrast, offer a local view at the nanoscale, revealing both structure and chemical composition.