Liverpool begin their Champions League campaign on Wednesday night as they welcome Spanish side Atletico Madrid to Anfield.To mark the occasion, Sky Bet are offering new customers who bet on the game a free £10 bet for every shot on target by Liverpool in the match, up to a maximum of £50, which can be claimed by following this link*.SKY BET – Get a free £10 bet for every Liverpool shot on target against Atletico Madrid – CLAIM HERELiverpool will be looking to make it five victories in a row on Wednesday night as they bid to kick off their Champions League campaign with victory over Atletico Madrid at Anfield.Arne Slot’s side are the reigning Premier League champions and have made a perfect start to the defence of their title with four wins and a 100% record leaving them sitting pretty three points clear at the top of the table.The Reds finished top of the inaugural league phase of the Champions League last season with seven wins from their eight matches and will be looking to achieve the same feat this time around.The six-times champions of Europe were knocked out at the Round of 16 stage though by eventual champions PSG, meaning the side haven’t reached the quarter final stage since their last run to the final in 2022.Atletico Madrid have had a slow start to their season so far, picking up only their first win of the season on Saturday night in a 2-0 victory over Villarreal, having lost their opener against Espanyol prior to stalemates against Elche and Alaves.Just five points from their opening four games leaves Diego Simeone’s side sat down in 11th place in La Liga.This will be the Spanish side’s 13th consecutive season competing in the Champions League, and have reached two finals in that period, though like Liverpool, were knocked out on penalties in the last 16 stage last season to their fierce rivals Real Madrid.The last time these two sides met came in the group of stage of this competition four years ago, with Liverpool winning home and away, though Atletico do have fond memories of playing at Anfield, having knocked the Reds on their two previous visits to Merseyside.How to watch Liverpool v Atletico MadridLocation: Anfield, LiverpoolDate and time: Wednesday 17th September 2025, 8pmHow to watch: TNT Sports 1, TNT Sports UltimateSKY BET – Get a free £10 bet for every Liverpool shot on target against Atletico Madrid – CLAIM HEREFree Bet OffersClaim £1000+ worth of free bets and betting offers from our partners – CLAIM HERE18+ gambleaware.org T&Cs Apply*New customers only. First single & e/w bet only. Odds of 1/1 or greater. Up to maximum of £50 in Free Bets. Free Bets credited within 72 hours. Free Bet stakes not included in returns. Free Bets are non-withdrawable. Free Bets expire after 30 days. Eligibility restrictions and further T&Cs apply.Commercial content notice: Taking one of the bookmaker offers featured in this article may result in a payment to talkSPORT. 18+. T&Cs apply. GambleAware.orgRemember to gamble responsiblyA responsible gambler is someone who:Establishes time and monetary limits before playingOnly gambles with money they can afford to loseNever chase their lossesDoesn’t gamble if they’re upset, angry or depressedGamcare – www.gamcare.org.ukGambleAware – www.gambleaware.orgFind our detailed guide on responsible gambling practices here.For help with a gambling problem, call the National Gambling Helpline on 0808 8020 133 or go to www.gamstop.co.uk to be excluded from all UK-regulated gambling websites.Most read in BettingFree Bets & betting offers 2025 - Claim £1000+ in bonuses for SeptemberChampions League betting offer: Get £10 back in cash if your bet builder loses with bet365Brentford v Aston Villa predictions and betting tips - Can Bees add to Villa misery?Athletic Bilbao v Arsenal prediction and betting tips - Can Gyokeres fire Gunners to win?Best horse racing betting sites September 2025 - Bonuses, tips & oddsBest Betting Sites UK: Best Bookmakers with a UK Licence 2025